| Record Information |
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| Version | 1.0 |
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| Created at | 2020-03-19 00:48:25 UTC |
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| Updated at | 2020-12-07 19:07:36 UTC |
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| CannabisDB ID | CDB000644 |
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| Secondary Accession Numbers | Not Available |
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| Cannabis Compound Identification |
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| Common Name | Methylhydrazine |
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| Description | Methylhydrazine also known as monomethylhydrazine is a methylated derivative of hydrazine. Methylhydrazine is a colorless liquid with an ammonia-like odor. Methylhydrazine is a volatile compound with the chemical formula CH3(NH)NH2. It is used as a rocket propellant in bipropellant rocket engines because it is hypergolic with various oxidizers such as nitrogen tetroxide (N2O4) and nitric acid (HNO3). This chemical is toxic and carcinogenic in small amounts, but it is easily stored in orbit providing moderate performance for very low fuel tank system weight. Another known use of MMH is in the synthesis of Suritozole. Methylhydrazine is naturally produced and it is believed to be the main cause of the toxicity of mushrooms of genus Gyromitra, especially the false morel (Gyromitra esculenta). In this case, methylhydrazine is formed by the hydrolysis of gyromitrin (PMID: 1238907 ). Methylhydrazine has been reported as a volatile compound detected in cannabis samples obtained through police seizure (PMID: 26657499 ). |
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| Structure | |
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| Synonyms | | Value | Source |
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| Monomethylhydrazine | MeSH | | Methyl-hydrazine | ChEMBL |
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| Chemical Formula | CH6N2 |
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| Average Molecular Weight | 46.07 |
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| Monoisotopic Molecular Weight | 46.0531 |
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| IUPAC Name | methylhydrazine |
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| Traditional Name | methyl hydrazine |
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| CAS Registry Number | 60-34-4 |
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| SMILES | CNN |
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| InChI Identifier | InChI=1S/CH6N2/c1-3-2/h3H,2H2,1H3 |
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| InChI Key | HDZGCSFEDULWCS-UHFFFAOYSA-N |
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| Chemical Taxonomy |
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| Description | Belongs to the class of organic compounds known as alkylhydrazines. These are organonitrogen compounds that containing a hydrazine group to which an alkyl group is attached. |
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| Kingdom | Organic compounds |
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| Super Class | Organic nitrogen compounds |
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| Class | Organonitrogen compounds |
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| Sub Class | Hydrazines and derivatives |
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| Direct Parent | Alkylhydrazines |
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| Alternative Parents | |
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| Substituents | - Alkylhydrazine
- Organopnictogen compound
- Hydrocarbon derivative
- Aliphatic acyclic compound
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| Molecular Framework | Aliphatic acyclic compounds |
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| External Descriptors | Not Available |
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| Ontology |
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| Role | Indirect biological role: |
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| Physical Properties |
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| State | Solid |
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| Experimental Properties | | Property | Value | Reference |
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| Melting Point | Not Available | Not Available | | Boiling Point | Not Available | Not Available | | Water Solubility | Not Available | Not Available | | logP | Not Available | Not Available |
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| Predicted Properties | [] |
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| Spectra |
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| EI-MS/GC-MS | | Type | Description | Splash Key | View |
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| Predicted GC-MS | Methylhydrazine, non-derivatized, Predicted GC-MS Spectrum - 70eV, Positive | Not Available | Spectrum | | Predicted GC-MS | Methylhydrazine, non-derivatized, Predicted GC-MS Spectrum - 70eV, Positive | Not Available | Spectrum |
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| MS/MS | | Type | Description | Splash Key | View |
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| Predicted MS/MS | Predicted LC-MS/MS Spectrum - 10V, Positive | splash10-0002-9000000000-b2c9419d08328c9ba78e | 2016-08-03 | View Spectrum | | Predicted MS/MS | Predicted LC-MS/MS Spectrum - 20V, Positive | splash10-0002-9000000000-d6977047857b54466baf | 2016-08-03 | View Spectrum | | Predicted MS/MS | Predicted LC-MS/MS Spectrum - 40V, Positive | splash10-001j-9000000000-0e2028d7cd892e59de4e | 2016-08-03 | View Spectrum | | Predicted MS/MS | Predicted LC-MS/MS Spectrum - 10V, Negative | splash10-0002-9000000000-a356a48951f55bb237cd | 2016-08-03 | View Spectrum | | Predicted MS/MS | Predicted LC-MS/MS Spectrum - 20V, Negative | splash10-002b-9000000000-8f6134f76c05cb162a38 | 2016-08-03 | View Spectrum | | Predicted MS/MS | Predicted LC-MS/MS Spectrum - 40V, Negative | splash10-004j-9000000000-868188ec0737b16cb02b | 2016-08-03 | View Spectrum |
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| NMR | Not Available |
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| Pathways |
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| Pathways | Not Available |
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| Protein Targets |
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| Enzymes | Not Available |
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| Transporters | Not Available |
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| Metal Bindings | Not Available |
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| Receptors | Not Available |
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| Transcriptional Factors | Not Available |
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| Concentrations Data |
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| Not Available |
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| External Links |
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| HMDB ID | Not Available |
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| DrugBank ID | Not Available |
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| Phenol Explorer Compound ID | Not Available |
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| FoodDB ID | Not Available |
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| KNApSAcK ID | Not Available |
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| Chemspider ID | Not Available |
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| KEGG Compound ID | Not Available |
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| BioCyc ID | Not Available |
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| BiGG ID | Not Available |
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| Wikipedia Link | Not Available |
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| METLIN ID | Not Available |
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| PubChem Compound | 6061 |
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| PDB ID | Not Available |
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| ChEBI ID | Not Available |
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| References |
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| General References | - Pyysalo H: Some new toxic compounds in false morels, Gyromitra esculenta. Naturwissenschaften. 1975 Aug;62(8):395. doi: 10.1007/BF00625355. [PubMed:1238907 ]
- Rice S, Koziel JA: Characterizing the Smell of Marijuana by Odor Impact of Volatile Compounds: An Application of Simultaneous Chemical and Sensory Analysis. PLoS One. 2015 Dec 10;10(12):e0144160. doi: 10.1371/journal.pone.0144160. eCollection 2015. [PubMed:26657499 ]
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